Framebuilders - Alternatives to paint/powder? Gun bluing?

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I was wondering if anyone here had ever (seen/heard of) using gun bluing instead of paint as a frame finish?
unterhausen
06-22-11, 09:40 AM
yes, I've heard of it. No, I don't remember what was said. Don't think it's rust proof.
Live Wire
06-22-11, 02:25 PM
Yup, been there, done that. Unterhausen is right, but damn it looks cool!
207564
mgeoffriau
06-22-11, 02:52 PM
Bluing isn't rust-proof at all, and it tends to wear thin pretty quickly (see the muzzle finish of old police revolvers worn through from holstering).
Now, for a more utilitarian finish, Parkerizing or a Tenifer/Melonite might be interesting on a bike frame.
OK, good to know the durability isn't there.
What about Titanium Nitride, the gold-ish color stuff they vapor deposit on high end tools and drill bits?
Parkerising isn't much more durable, it's a thin layer of manganese phosphate laid down from an autocatalytic acid process, so you have to be careful with it on high-strength steels. The aerospace community mandates post-treatment bakes for anything over about 1000MPa UTS with any form of acid-bath treatment, for good reason.
And even then, it's not particularly anticorrosive. You have to oil the rough surface, and keep re-oiling it if it's not to be used in an anhydrous environment, y'know, like, the world outside.
Titanium nitride is fine for decorative coatings and such, but it's rather brittle and prone to spalling if the substrate is too ductile and tough, like, for example, a bike frame. It goes onto HSS tools because they're treated to over 60 Rockwell C and full of massive carbides, which make them break before they deform, thus ensuring the brittle coating has a substrate that behaves the same. A number of manufacturers have moved from titanium nitride to titanium aluminium nitride, which is a pleasing dark blue colour and much more forgiving.
Goltec used to throw down TiN on anything they sold, but that was things like hub bodies, casettes etc. I have no anecdotal evidence on how long it lasted on them, I'm afraid.
Oh, and it's not particularly sacrificial as a coating.
Actually, as an aside, I've discovered an almost-paint that may be of interest. I'm trying it out on a couple of resprays. It's a zinc-epoxy ester protective primer type thing, that's about 95% metal when it's cured, and takes a good polish if you put down about three coats to 50-70 microns. I'm using it as fake plate on scuffed aluminium fork crowns too, to see how it goes.
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