Join Date: Jan 2008
Location: Beaverton, OR
Bikes: 2013 Kona Jake, 2015 Kona Jake the Snake, 2008 Kona Major Jake, 2013 Kona Jake the Snake, 2006 Kona Kula, 2012 Ridley Excalibur, 2001 LeMond Buenos Aires, 1984 Pinarello Gran Turismo, 1982 Trek 614, 1979 Austro-Daimler, 1974 Steyr Clubman
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I've used 700x35 tires with Open Pros and had zero problems. It seems to me that 103 psi is more pressure than you'd ever want in a 700x32 tire anyway, regardless of the rim. I'm guessing, though, that your main surprise is that they'd even give a maximum pressure for a tire that's outside their recommended size range. If you ask me, that size recommendation is very conservative.
FWIW, my 2008 Kona Jake came stock with 700x35 tires on Alex AT-450 rims, which are several millimeters narrower than Open Pros. That combination has never given me any trouble either.