I belive for Presta.... the small while ring goes in first, the the big white collar goes in with the pin pointing toward the hose, then the black rubber part with the the smaller opening facing towards the the screwon cap.
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“One morning you wake up, the girl is gone, the bikes are gone, all that's left behind is a pair of old tires and a tube of tubular glue, all squeezed out"
Sugar "Kane" Kowalczyk