SBinNYC hit the nail on the head.
I found a small bit if wire on the inside of the tire. It was thinner than a staple. The hole in the tube was smaller than a needle.
I patched it and filled it. Interesting to note that CO2 pumps do not fully inflate the tube. I had o top it off at the LBS. Of course this is my first time using the contraption.
Also my tires are full of holes, cut, gashes, and other nicks. However, the tire is still ok and this is first real trouble I have had with it.
I run it at 115 in the rear because the Vittoria bounces too much at higher pressures.