Is it sinful to mix brake styles? I use a front V-brake and a big rear disc brake on our tandem - usually at the same time! Just call me a brake mixer.
For what it's worth - have never panic stopped on this bike.
Worry over an endo is absolutely not a reason for using both brakes on a tandem.
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Bacchetta Giro A20, RANS V-Rex, RANS Screamer