Joined: Jan 2010
Posts: 9,813
Likes: 1,790
From: Northern California
Bikes: Cheltenham-Pedersen racer, Boulder F/S Paris-Roubaix, Varsity racer, '52 Christophe, '62 Continental, '92 Merckx, '75 Limongi, '76 Presto, '72 Gitane SC, '71 Schwinn SS, etc.
There a lot of coatings used on cable inner wires, even Shimano's best ones have some Teflon or similar iir.
I would totally avoid (inner) cables with plastic covering though, which so often shreds and binds the cable in the housing.
The black-coated Slik-Whips and similar cables (thin, hard coating) have worked well for me.
Remember that brake housings always use metal ferrules where needed, while shift housings can use appropriately-size plastic or metal ferrules (sealed or un-sealed) where needed.
Pre-stress the cable tension (mostly to settle ferrules and cable ends) prior to final adjustment, but not to the point of damaging cables, housings or shifters.