Looking at the lack of tension on your chain in the small small combo makes me shudder, please dont attempt to ride that out on the road, just shift to big ring, there shouldn't be chain droop even in that combination of gearing and it's really not a good idea to ride in small small anyway due to lack of tension even when there isnt the blackness shown in your photo.

Deraillieurs have a maximum capacity rating for a reason, if your choice of gearing means that you are outside of that range then you should change your deraillieur or change to a lower range cassette