That screw is called a reach adjuster. It can adjust how far the levers are from the bar in their at rest position. (ie screw it in and the levers move closer to the bar..............this movement comes out of your total throw however ) If you like the levers in their full out position, you don't need the screw.
As to using your existing screws, if the thread fits the pattern in the hole then they will work.
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