The dealer manual is easy to follow and very helpful on any adjustments.
Go to the Shimano downloads page for Di2, here:
si.shimano.com/#seriesList/51
and download & save the dm-ul0001-02.pdf Dealer's Manual.
Shift 3 cogs
You can do this with the e-tube free software, or have the LBS do it. It's much better than the default "shift all the cogs" on a long press.
I have my Di2 set to "shift 3 cogs" on a half second (or longer) "long press". So at the base of a hill, press both bottom paddles with a long press to go to the 34 and to three smaller cogs. Slick. A long press on both top paddles goes to the big ring and three larger cogs at the top of a hill.
Wiring tool
Make sure they provide the
Di2 wire tool. It should come with the bike. It makes plugging or unplugging the wiring much easier.