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Can CO2 Cartridges Explode?

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Old 06-15-11 | 05:23 PM
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Can CO2 Cartridges Explode?

Ever had a CO2 cartridge explode, whether left in the sun or stuffed in a gear bag on a 100F day?
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Old 06-15-11 | 05:33 PM
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I have them in my gear bag when it 95 and I've had them in my gear at 11,000 ft. So far, no exploding saddle packs.
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Old 06-15-11 | 05:41 PM
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Originally Posted by gbiker
Ever had a CO2 cartridge explode, whether left in the sun or stuffed in a gear bag on a 100F day?
I think you need to heat one above 130 Fahrenheit, so unless you're riding around the Saudi desert in summer, I wouldn't worry about it.
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Old 06-15-11 | 06:30 PM
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If something is under pressure, then it's possible. Have you checked the box they come in, or maybe the side of the bottle. I'd think a temp limit would be shown if it could be a problem.
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Old 06-15-11 | 07:13 PM
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Since an explosion describes a kind of uncontrolled combustion and CO2 isn`t combustable - it can`t explode.

So lets assume you mean burst due to temperature or pressure extremes. Due to its design (the end you pierce is the weakest part of the cylinder) the worst that could possibly happen is the cylinder could vent through that end. But I`ve never had or heard of that happening myself.
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Old 06-15-11 | 07:18 PM
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I've seen a max. temperature listing of 50C which is only 122F, so it could be an issue if left in a parked car on a sunny day. But I'm sure there's a pretty good safety margin above the specified max. temp.
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Old 06-15-11 | 07:40 PM
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When I was a kid I was given several hundred cartridges for use with pellet guns. I used a bunch for that purpose, but eventually got bored and started experimenting. The short version is that I found a number of ways to get the ends to rupture (moderately exciting, kind of loud) but never could get them to "explode", even by tossing them into the fire, duct taping them to railroad tracks, or shooting them with the pellet gun. So even if you encounter extreme conditions, you might get them to vent as described by Burton above, but I'd be pretty surprised if you could get one to rupture out the side, mimicking an explosion.
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Old 06-15-11 | 07:52 PM
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Originally Posted by Six jours
When I was a kid I was given several hundred cartridges for use with pellet guns. I used a bunch for that purpose, but eventually got bored and started experimenting. The short version is that I found a number of ways to get the ends to rupture (moderately exciting, kind of loud) but never could get them to "explode", even by tossing them into the fire, duct taping them to railroad tracks, or shooting them with the pellet gun. So even if you encounter extreme conditions, you might get them to vent as described by Burton above, but I'd be pretty surprised if you could get one to rupture out the side, mimicking an explosion.

+1 ...... Love it
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Old 06-15-11 | 07:58 PM
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It's a wonder any adolescent males make it to adulthood, isn't it?
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Old 06-15-11 | 08:02 PM
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nope, many are Darwin Award "winners"
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Old 06-15-11 | 08:21 PM
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https://www.merriam-webster.com/dictionary/explode

1. b. under intransitive verb

b : to burst violently as a result of pressure from within
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Old 06-15-11 | 09:17 PM
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^ Yep, explosions can happen without combustibles.

Anyway, no probs with them in my saddle bag in 95F heat, nor with a new box of Daisy CO2 cartridges sitting on my doorstep in the hot sun. I'll find out how they hold up at 14,265' or so this summer. The box says don't heat above 140F, but the cartridges themselves say 120F (WTF?). Anyhow, I'm pointing them forward in my saddle bag so that if they do burst and act like missiles, I'll get a boost.
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Old 06-15-11 | 09:24 PM
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This is from paintball, but the chart works for any CO2 cartridge:



The 'Minimum blowout' line is the burst disc pressure on refillible CO2 cartridges. 12/16 gram cartridges may have higher burst pressures, but it likely works as a rough guide.
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Old 06-15-11 | 09:39 PM
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Originally Posted by Six jours
When I was a kid I was given several hundred cartridges for use with pellet guns. I used a bunch for that purpose, but eventually got bored and started experimenting. The short version is that I found a number of ways to get the ends to rupture (moderately exciting, kind of loud) but never could get them to "explode", even by tossing them into the fire, duct taping them to railroad tracks, or shooting them with the pellet gun. So even if you encounter extreme conditions, you might get them to vent as described by Burton above, but I'd be pretty surprised if you could get one to rupture out the side, mimicking an explosion.
Goofing with friends as a teen and threw some in a fire once too. They didn't explode but did wizz around bouncing off trees.
It's a wonder no one put their eye out.
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Old 06-15-11 | 11:03 PM
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Originally Posted by Burton
Since an explosion describes a kind of uncontrolled combustion and CO2 isn`t combustable - it can`t explode.

So lets assume you mean burst due to temperature or pressure extremes. Due to its design (the end you pierce is the weakest part of the cylinder) the worst that could possibly happen is the cylinder could vent through that end. But I`ve never had or heard of that happening myself.
You don't need combustion for an explosion. An explosion is defined as a rapid increase in volume and release of energy. It can be caused by bursting due to internal pressure. Pressure vessels do indeed 'explode' without a chemical component.

The pressure in a 9 g CO2 cartridge is 850 psi at 72F. The pressure doesn't climb all that fast with temperature. It would reach 975 psi at 120 F which is high but not horribly high. The burst disc on the top of the cartridge blows out around 2200 psi which isn't reached until around 1200F...think camp fire.

If the burst disc ruptured, the difference between that and an explosion would be a matter of semantics. If you were near one, it'd make a hell of a noise and you'd probably call it an explosion.
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Old 06-16-11 | 06:01 AM
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Originally Posted by Pete In Az
Explosion was originally a description used to describe the detonation of explosives. Like lots of other words, many have been used and abused simply to add drama to sentences so now sprinters `explode out of the starting gates`. I hope they don`t hurt themselves too much in the process.

Check out the wikipedia for explosion and you won`t find anything not associated with explosives. Pressure vessles rupture or burst. They only explode when the contents are flamable and heat causes them to rupture and then explode when the contents ignite.

This may be largely symantics but since the OP posted a safety concern I think it was appropriate to point out the difference.
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Old 06-16-11 | 06:20 AM
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Originally Posted by cyccommute
You don't need combustion for an explosion. An explosion is defined as a rapid increase in volume and release of energy. It can be caused by bursting due to internal pressure. Pressure vessels do indeed 'explode' without a chemical component.
Oh oh! I'm sensing another word (like fume) that has a special meaning that only applies to certain people. The most recent word to bother me is bladder. I pee from my bladder. I drink from my hydration reservoir.
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Old 06-16-11 | 07:56 AM
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Originally Posted by Retro Grouch
Oh oh! I'm sensing another word (like fume) that has a special meaning that only applies to certain people. The most recent word to bother me is bladder. I pee from my bladder. I drink from my hydration reservoir.
Words have multiple meanings. That's the way English...at least American English...works. When you drink from your hydration reservoir are you drinking from a large lake that is used to store water? Or is your bladder a a distensible membranous sac, an inflated fruit or vesicle in various plants, a fluid-filled cavity in metacestodes of some Trypanorhyncha, Tetraphyllidea and Cyclophyllidea, a bag that fills with air, a bag that fills with water, or losed-end, thick rubber, cylindrical shaped piece that contains the nitrogen gas in shock absorber.

Originally Posted by Burton
Explosion was originally a description used to describe the detonation of explosives. Like lots of other words, many have been used and abused simply to add drama to sentences so now sprinters `explode out of the starting gates`. I hope they don`t hurt themselves too much in the process.

Check out the wikipedia for explosion and you won`t find anything not associated with explosives. Pressure vessles rupture or burst. They only explode when the contents are flamable and heat causes them to rupture and then explode when the contents ignite.

This may be largely symantics but since the OP posted a safety concern I think it was appropriate to point out the difference.
You need to read further. From the Wikipedia explosion topic

Electrical and magnetic
A high current electrical fault can create an electrical explosion by forming a high energy electrical arc which rapidly vaporizes metal and insulation material. This arc flash hazard is a danger to persons working on energized switchgear. Also, excessive magnetic pressure within an ultra-strong electromagnet can cause a magnetic explosion.

Mechanical and vapour
Strictly a physical process, as opposed to chemical or nuclear, e.g., the bursting of a sealed or partially-sealed container under internal pressure is often referred to as a 'mechanical explosion'. Examples include an overheated boiler or a simple tin can of beans tossed into a fire.

Boiling liquid expanding vapour explosions are one type of mechanical explosion that can occur when a vessel containing a pressurized liquid is ruptured, causing a rapid increase in volume as the liquid evaporates. Note that the contents of the container may cause a subsequent chemical explosion, the effects of which can be dramatically more serious - such as a propane tank in the midst of a fire. In such a case, to the effects of the mechanical explosion when the tank fails are added the effects from the explosion resulting from the released (initially liquid and then almost instantaneously gaseous) propane in the presence of an ignition source. For this reason, emergency workers often differentiate between the two events.
Explosion was not originally used to describe the detonation of explosives. The etymology of the word is far from that. From the Online Etymology dictionary

explode
1530s, "to reject with scorn," from L. explodere "drive out or off by clapping, hiss off, hoot off," originally theatrical, "to drive an actor off the stage by making noise," hence "drive out, reject" (a sense surviving in an exploded theory), from ex- "out" (see ex-) + plaudere "to clap the hands, applaud," of uncertain origin. Athenian audiences were highly demonstrative. clapping and shouting approval, stamping, hissing, and hooting for disapproval. The Romans seem to have done likewise.
At the close of the performance of a comedy in the Roman theatre one of the actors dismissed the audience, with a request for their approbation, the expression being usually plaudite, vos plaudite, or vos valete et plaudite. [William Smith, "A First Latin Reading Book," 1890]

English used it to mean "drive out with violence and sudden noise" (1650s), later, "go off with a loud noise" (Amer.Eng. 1790); sense of "to burst with destructive force" is first recorded 1882; of population, 1959. Related: Exploded; exploding.
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Old 06-16-11 | 09:23 AM
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And Cyccommute delivers a fatal blow...
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Old 06-16-11 | 09:46 AM
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CO2 in containers is funny stuff. It's actually sensitive to how full the container is between liquid and gas. Check out this chart. It actually shows that for a full cartridge cycommute's figures for the higher temperatures are low if the cartridges are filled to capacity;



It's an odd chart but if you look at the % fill line for 100% and go up to the 120F line the pressure is actually up around 1900 psi. And if the tops on the cartridges are set to blow off at around 2200 or so that is going to occur at around 130 by extrapolation since there's no temperature lines beyond 120.

The funny flat lines under the lowest curve are indicative of the bi-phase state where there's liquid and gas in the container at the same time. At temperatures and fill amounts in that area the pressure will remain constant over a wide range of fill amounts. But at around just under 90F the CO2 converts to all gas with no liquid content.

Mind you once you start to vent the gas off during use or in the event of a burst end cap the temperature will fall fast even on an overheated cartridge.
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Old 06-16-11 | 10:09 AM
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Originally Posted by BCRider
CO2 in containers is funny stuff. It's actually sensitive to how full the container is between liquid and gas. Check out this chart. It actually shows that for a full cartridge cycommute's figures for the higher temperatures are low if the cartridges are filled to capacity;



It's an odd chart but if you look at the % fill line for 100% and go up to the 120F line the pressure is actually up around 1900 psi. And if the tops on the cartridges are set to blow off at around 2200 or so that is going to occur at around 130 by extrapolation since there's no temperature lines beyond 120.

The funny flat lines under the lowest curve are indicative of the bi-phase state where there's liquid and gas in the container at the same time. At temperatures and fill amounts in that area the pressure will remain constant over a wide range of fill amounts. But at around just under 90F the CO2 converts to all gas with no liquid content.

Mind you once you start to vent the gas off during use or in the event of a burst end cap the temperature will fall fast even on an overheated cartridge.
Gah, now I am wanting to see how many cubic inches my 16g CO2 cartridges are to see what "percent full" they are. I'm sure I'll forget by the time I get home, though
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Old 06-16-11 | 10:23 AM
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Don't panic over it. Besides your 16gm cartridges hold 16 gms of CO2. They are rated by weight, not volume, since at room temperature the CO2 is mostly a liquid as far as the mass which is liquid and the mass which is gas. If you want to check it google for CO2 liquid density and figure that 15.5 grams of the 16 is likely liquid. Same with CO2 fire extinguishers and paintball bottles. They are rated by weight for a full fill that produces the correct safe fill volume.

If you really want to scare yourself saw an empty cartridge in half lengthwise some time. The walls on these things look pop can thin. On second thought don't. It'll scare you so badly that you'll never want to hold one again knowing how much pressure is inside and what the metal could do if one were to suddenly decide to burst....

I KID! I KID! But the walls really ARE thin.
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Old 06-16-11 | 02:10 PM
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No!
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Old 06-16-11 | 02:15 PM
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From: Gaseous Cloud around Uranus
You can have a steam explosion(steam engine)...water gets big(1000x)...fast.
It throws 40,000 pound airplanes from ships...

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Old 06-16-11 | 02:24 PM
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Originally Posted by somedood
Gah, now I am wanting to see how many cubic inches my 16g CO2 cartridges are to see what "percent full" they are. I'm sure I'll forget by the time I get home, though
The simple way is to have a measuring cup of water and measure how much the level goes up when you dunk the cart... true volume will be a little less of course, but pretty close.
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